| Name | Team | Year | Position | Alma Mater | |
| 1 | Jacob Turner | 1st Rd. - Detroit Tigers | 2009 | Pitcher | Westminster High School |
| 2 | Blair Springfield | Chicago Cubs | 2009 | Outfielder | MacArthur High |
| 3 | Luke Voit | Kansas City Royals | 2009 | Catcher | Lafayette High School |
| 4 | Dane Opel | Washington Nationals | 2009 | Outfielder | Edwardsville High School |
| 5 | Evan Button | Arizona Diamondbacks | 2009 | Infielder | Ole Miss |
| 6 | Tim Clubb | Chicago Cubs | 2009 | Pitcher | Missouri State |
| 7 | Kyle Mach | San Francisco Giants | 2009 | Infielder | Mizzou |
| 8 | Rob Wort | Washington Nationals | 2009 | Pitcher | Jefferson College |
| 9 | Nate Goro | Detroit Tigers | 2009 | Infielder | Lafayette High School |
| 10 | Vince Howard | Atlanta Braves | 2009 | Outfielder | Sikeston High School |
| 11 | Scott Summerfeld | Cleveland Indians | 2009 | Catcher | Parkway South High School |
| 12 | Stephen Kolscheen | Philadelphia Phillies | 2009 | Pitcher | Cowley County Junior College |
| 13 | Dallas Hord | Florida Marlins | 2009 | Catcher | Missouri State |
| 14 | Ben Tschepikow | Kansas City Royals | 2009 | Infielder | University of Arkansas |
| 15 | Brayden Drake | San Diego Padres | 2009 | Infielder | Missouri State |
| 16 | Franco Broyles | Colorado Rockies | 2009 | Outfielder | Fayetteville High School |
| 17 | Kevin Kuntz | Kansas City Royals | 2009 | Infielder | Tulsa Union High School |
| 18 | Buddy Baumann | Kansas City Royals | 2009 | Pitcher | Missouri State |
| 19 | Dallas Kechuel | Houston Astros | 2009 | Pitcher | University of Arkansas |
| 20 | Taylor Freeman | New York Yankees | 2009 | Catcher | McNeese State |
| 21 | Jason Hagerty | San Diego Padres | 2009 | Catcher | University of Miami (Florida) |
| 22 | Jim Klocke | St. Louis Cardinals | 2009 | Catcher | Southeast Missouri State |
| 23 | Nick Fransworth | Anaheim Angels | 2008 | Infielder | Tulsa Union High School |
| 24 | Chase Huchingson | Houston Astros | 2008 | Pitcher | University of Arkansas |
| 25 | Zach Grimmett | Houston Astros | 2008 | Pitcher | Beggs High School |
| 26 | Aaron Shafer | Chicago Cubs | 2008 | Pitcher | Wichita State |
| 27 | Blake Tekotte | San Diego Padres | 2008 | Outfielder | Iuniversity of Miami |
| 28 | Jacob Priday | Houston Astros | 2008 | Outfielder | Mizzou |
| 29 | Chris Hicks | Houston Astros | 2008 | Pitcher | Georgia Tech |
| 30 | David Phelps | New York Yankees | 2008 | Pitcher | Notre Dame |
| 31 | John Hellweg | Anaheim Angels | 2008 | Pitcher | Florida Community College |
| 32 | Derrick Phillips | Washinton Nationals | 2008 | Outfielder | Westminster |
| 33 | Charlie Lowell | Texas Rangers | 2008 | Pitcher | Winnfield High School |
| 34 | Matt Frevert | St. Louis Cardinals | 2008 | Pitcher | Missouri State |
| 35 | Tim Clubb | Tampa Bay Rays | 2008 | Pitcher | Missouri State |
| 36 | Casey Moore | Detroit Tigers | 2008 | Catcher | St. Louis University |
| 37 | Nick Schmidt | 1st. Rd. - San Diego Padres | 2007 | Pitcher | University of Arkansas |
| 38 | Ross Detwiler | 1st. Rd. - Washington Nationals | 2007 | Pitcher | Missouri State Univ. |
| 39 | Drew Benes | Cincinnati Reds | 2007 | Infielder | Westminster High School |
| 40 | Sean Loggins | Anaheim Angels | 2007 | Catcher | McCluer North |
| 41 | John Hellweg | Florida Marlins | 2007 | Pitcher | St. Dominic |
| 42 | Brock Bond | San Francisco Giants | 2007 | Infielder | University of Missouri |
| 43 | Evan Frey | Arizona Diamondbacks | 2007 | Outfielder | University of Missouri |
| 44 | John Flanagan | Chicago White Sox | 2007 | Pitcher | Belleville West |
| 45 | Parker Frazier | Colorado Rockies | 2007 | Pitcher | Tulsa Bishop Kelly |
| 46 | Matt Lawson | Texas Rangers | 2007 | Infielder | Missouri State Univ. |
| 47 | Bobby Spain | Pittsburgh Pirates | 2007 | Infielder | Oklahoma City Univ. |
| 48 | Matt Hoffman | Detroit Tigers | 2007 | Pitcher | Owasso Oklahoma High School |
| 49 | John Fritsche | St. Louis Cardinals | 2007 | Pitcher | Oklahoma State Univ. |
| 50 | Chase Huchingson | Texas Rangers | 2007 | Pitcher | Fayetteville Arkansas High School |
| 51 | J.C. Casey | Chicago Cubs | 2007 | Pitcher | Springfield Kickapoo High School |
| 52 | Tyler Clark | Chicago Cubs | 2007 | Pitcher | Springfield Catholic |
| 53 | Stephen Kohlscheen | Florida Marlins | 2007 | Pitcher | Norma North High School |
| 54 | Max Scherzer | 1st. Rd. - Arizona Diamondbacks | 2006 | Pitcher | University of Missouri |
| 55 | Devon Collis | Colorado Rockies | 2006 | Pitcher | University of Arkansas |
| 56 | Nathan Culp | San Diego Padres | 2006 | Pitcher | University of Missouri |
| 57 | Chris Nash | Cleveland Indians | 2006 | Infielder | Marquette |
| 58 | John Wilson | LA Dodgers | 2006 | Infielder | St. Charles |
| 59 | Mike Ponitious | Cleveland Indians | 2006 | Pitcher | Wentzville/Holt |
| 60 | Kent Gerst | Chicago White Sox | 2006 | Outfielder | Ft. Zumwalt West |
| 61 | Travis Mitchell | St. Louis Cardinals | 2006 | Outfielder | Parkway Central |
| 62 | Brett Sinkbeil | 1st Rd. - Florida Marlins | 2006 | Pitcher | Missouri State Univ. |
| 63 | Blake Parker | Chicago Cubs | 2006 | Catcher | Univ. of Arkansas |
| 64 | John Freeman | Detroit Tigers | 2006 | Catcher | Carney HS |
| 65 | Michael Hubbard | Florida Marlins | 2006 | Outfielder | Univ. of Arkansas Fort Smith |
| 66 | Sean Toler | Colorado Rockies | 2005 | Pitcher | Parkway South |
| 67 | Chris Nash | LA Angels | 2005 | Infielder | Marquette |
| 68 | Aaron Schafer | Cleveland Indians | 2005 | Pitcher | Troy |
| 69 | Adam Hall | Tampa Bay Devil Rays | 2005 | Pitcher | Pacific |
| 70 | Chris Frey | Colorado Rockies | 2005 | Outfielder | Highland/Arizona |
| 71 | Josh Alley | San Diego Padres | 2005 | Outfielder | Anna Jonesborro/Tenn. |
| 72 | Sam Lecure | Cincinnati Reds | 2005 | Pitcher | Jeff City Halias/Texas |
| 73 | Joe Muich | New York Yankees | 2005 | Catcher | DeSmet/Wichita |
| 74 | Mike Phelps | Chicago Cubs | 2005 | Pitcher | Hazelwood West/CMSU |
| 75 | Adam Howard | Florida Marlins | 2005 | Pitcher | North County/Meramec |
| 76 | Jesse Barr | New York Yankees | 2005 | Pitcher | McCluer/Missouri Baptist |
| 77 | Joe Simokaitis | Chicago Cubs | 2005 | Infielder | St. Marys/Nebraska |
| 78 | Blake Dewitt | 1st Rd. - LA Dodgers | 2004 | Infielder | Sikeston |
| 79 | Scott Elbert | 1st Rd. - LA Dodgers | 2004 | Pitcher | Sineca |
| 80 | Lucas Harrell | Chicago White Sox | 2004 | Pitcher | Ozark |
| 81 | Todd Stein | Arizona Diamondbacks | 2004 | Pitcher | Ladue/Illinois State |
| 82 | Dusty Renfrow | Arizona Diamondbacks | 2004 | Pitcher | Jefferson CC |
| 83 | Bobby Spain | San Diego Padres | 2004 | Infielder | Oklahoma City Univ. |
| 84 | Sal Fersella | St. Louis Cardinals | 2003 | Outfielder | Vianney/SIUC |
| 85 | Andy Sides | New York Mets | 2003 | Pitcher | DeSoto |
| 86 | Lucas May | LA Dodgers | 2003 | Infielder | Parkway West |
| 87 | Max Scherzer | Philadelphia Phillies | 2003 | Pitcher | Parkway Central |
| 88 | Adam Johnsen | St. Louis Cardinals | 2003 | Pitcher | Pacific/Xavier |
| 89 | Brett Sinkbeil | St. Louis Cardinals | 2003 | Pitcher | Missouri State Univ. |
| 90 | Jason Sullivan | Chicago White Sox | 2003 | Pitcher | Crowder/Nicholls State |
| 91 | Sam Lecure | Philadelphia Phillies | 2002 | Pitcher | Jeff City Halis |
| 92 | Ronnie Ray | Anaheim Angels | 2002 | Pitcher | Pacific |
| 93 | Kyle McLellan | St. Louis Cardinals | 2002 | Pitcher | Hazelwood West |
| 94 | Wes Jaillet | St. Louis Cardinals | 2002 | Pitcher | Lafayette/SLU |
| 95 | Jamin Huchingson | Chicago White Sox | 2002 | Pitcher | |
| 96 | Dan Shouse | St. Louis Cardinals | 2001 | Pitcher | Marquette/SLU |
| 97 | Matt Roguse | Arizona Diamondbacks | 2001 | Pitcher | |
| 98 | Ryan Howard | Philadelphia Phillies | 2001 | Infielder | Lafayette/SMS |
| 99 | Jonathan Estes | St. Louis Cardinals | 2001 | Pitcher | Ritenour |
| 100 | Robert Mosby | Kansas City Royals | 2000 | Pitcher | East St. Louis |
| 101 | Garrett Bauer | Texas Rangers | 2000 | Pitcher | Lafayette |
| 102 | Peter Stonard | New York Yankees | 2000 | Infielder | Clayton |
| 103 | Jr. Warner | California Angels | 2000 | Outfielder | Priory/Mizzou |
| 104 | Don Rogers | Colorado Rockies | 2000 | Infielder | DeSmet |
| 105 | Bob Keppel | 1st Rd. - New York Mets | 2000 | 1st Round | DeSmet Pitcher |
| 106 | Ken Lutz | Cincinnati Reds | 1999 | Pitcher | Collinsville |
| 107 | Jared Lawson | Philadelphia Phillies | 1998 | Pitcher | Potosi |
| 108 | Dustin Brewer | Baltimore Orioles | 1998 | Pitcher | Granite City |
| 109 | Luke Miller | New York Yankees | 1998 | Pitcher | Rolla |
| 110 | Corey Lawson | New York Yankees | 1998 | Pitcher | Windsor |
| 111 | Tim Diekes | Seattle Mariners | 1998 | Catcher | Mehlville |
| 112 | David Fowler | New York Yankees | 1998 | Outfielder | McClure |
| 113 | Jay Crawford | Oakland A's | 1997 | Pitcher | Chatham G. |
| 114 | Tony Hauslandin | Arizona Diamondbacks | 1997 | Pitcher | DeSmet/SLU |
| 115 | Steve Coyler | LA Dodgers | 1997 | Pitcher | Fort Zumwalt South |
| 116 | Dennis Tankers | Boston Red Sox | 1997 | Pitcher | St. Charles |
| 117 | Alvin Morrow | Milwaukee Brewers | 1997 | Outfielder | Kirkwood |
| 118 | Lance Burkart | Montreal Exposes | 1997 | Catcher | Hazelwood West/SEMW |
| 119 | Andrew Prater | Pittsburgh Pirates | 1996 | Pitcher | McClure N. |
| 120 | Brett Bredensteiner | Chicago White Sox | 1994 | Outfielder | Duchesne |
| 121 | Mike Brown | San Diego Padres | 1993 | Infielder | Hazelwood West |